Introduction.- Nickel-1,2-o-Carboryne Complexes.- Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes.- Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes.- Nickel-Catalyzed Regioselective [2]2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes.- Palladium/Nickel-Cocatalyzed [2]2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes.- Conclusion.- Experimental Section.
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