This monograph addresses two significant related questions in complex geometry: the construction of a Chern character on the Grothendieck group of coherent sheaves of a compact complex manifold with values in its Bott-Chern cohomology, and the proof of a corresponding Riemann-Roch-Grothendieck theorem. One main tool used is the equivalence of categories established by Block between the derived category of bounded complexes with coherent cohomology...